Home >  Term: diethyl ketone
diethyl ketone

A volatile organic compounds whose formula is C5H10O. It is released from combustion exhaust and solvent use. This is a compound that undergoes photolysis around the wavelengths of 302-320 nm and produces the acyl radical. That reactive species reacts with molecular oxygen to form a peroxide which can oxidize NO to NO2 :

CH3CH2C(=O)CH2CH3 + hv ---> CH3CH2C(=O). + CH3CH2.

CH3CH2C(=O). + O2 ---> CH3CH2C(=O)O2.

CH3CH2C(=O)O2. + NO ---> NO2 + CH3CH2CO2.

And finally the acylate radical CH3CH2CO2. can further oxidize NO to NO2, providing even more ammunition to make ozone while the sun shines (see nitrogen dioxide and ozone). ~Subramanian, M. S. ; Environmental Chemistry Analysis; Module 3. 3 Organic Air Pollutants; Department of CHemistry; India Institute of Technology, Madras, India`

0 0

Creator

  • Joseal
  •  (Silver) 533 points
  • 100% positive feedback
© 2025 CSOFT International, Ltd.